When you configured the openfire server did you give it a fully qualified domain name (i.e. openfire.domain.com)? Does the openfire name used in the config have a valid dns entry? Is the firewall of the server configured to allow port 5222?
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When you configured the openfire server did you give it a fully qualified domain name (i.e. openfire.domain.com)? Does the openfire name used in the config have a valid dns entry? Is the firewall of the server configured to allow port 5222?